Save 20% on select titles with code HIDDEN24 - Shop The Sale Now
Carbon Capture and Storage (CCS). The CO2 stream, captured from power plants contains highly corrosive impurities including H2O vapor, oxygen, and hydrogen sulfide. This paper presents our study on corrosion of pipeline steel in sc-CO2 containing H2O, H2S and/or O2 impurities in an autoclave.
We are unable to complete this action. Please try again at a later time.
If this error continues to occur, please contact AMPP Customer Support for assistance.
Error Message:
Please login to use Standards Credits*
* AMPP Members receive Standards Credits in order to redeem eligible Standards and Reports in the Store
You are not a Member.
AMPP Members enjoy many benefits, including Standards Credits which can be used to redeem eligible Standards and Reports in the Store.
You can visit the Membership Page to learn about the benefits of membership.
You have previously purchased this item.
Go to Downloadable Products in your AMPP Store profile to find this item.
You do not have sufficient Standards Credits to claim this item.
Click on 'ADD TO CART' to purchase this item.
Your Standards Credit(s)
1
Remaining Credits
0
Please review your transaction.
Click on 'REDEEM' to use your Standards Credits to claim this item.
You have successfully redeemed:
Go to Downloadable Products in your AMPP Store Profile to find and download this item.
Selected Fe- and Ni-based alloys and superalloys have been exposed in 99.995% supercritical carbon dioxide for 500 hours at 750°C and 200 bar. Post exposure examination provided information on corrosion rates, microstructural evolution and the carbon concentration in the exposed materials.
Using supercritical CO2 (sCO2) as a working fluid is being explored for a number of power generation technologies including fossil, nuclear, geothermal, concentrating solar power (CSP) and waste heat recovery1-7. The various sCO2 cycles are attractive because of the low critical point (31°C/73.8 bar) and the reduced work of compression compared to an ideal gas. While CO2 is sometimes described as inert, there is a long history of component degradation in subcritical and supercritical CO2 and a particular concern about internal carburization8-16.
In recent years, several novel technologies have been proposed and developed to produce energy in a clean and sustainable way. However, in the foreseen future, fossil fuel will still be the major source to meet our needs on energy.1 The combustion of fossil fuel for power and heat is always accompanied by CO2 emission, which is believed to be in large correlation to global warming.2 To control the CO2 emission and reduce the negative effects, carbon capture and storage (CCS) has been rapidly developed in fossil fuel combustion power plants.3, 4 One of the crucial parts of CCS is the longdistance transportation of CO2, during which a large amount of captured CO2 is transported to storage sites. Pipeline network is chosen as transportation system due to its high efficiency and moderate cost.5 And the transported CO2 streams are usually compressed into supercritical CO2 (s-CO2).6
Over the years, the supercritical carbon dioxide (s−CO2) Brayton cycle has been developed as a promising working fluid to replace supercritical water (s−H2O) Rankine cycle. It could be used in various energy systems, including Generation IV nuclear reactors, concentrated solar power plants, fossil fuel thermal power plants, waster heat recovery, etc. due to its merits of high thermal efficiency, simple physical footprint, compact equipment size, high flexibility on operation, simple layout, compact turbomachinery.1
Supercritical CO2 (sCO2) has many attractive features as a working fluid including its low critical point (31°C/73.8 bar) and the reduced work of compression compared to an ideal gas. Thus, it is being explored for many different applications including fossil, nuclear, geothermal, concentrating solar power (CSP) and waste heat recovery. However, CO2 environments are known to carburize steels6-20 which limits their usage to lower temperatures (450°C21 for 9%Cr steels) than in steam boilers.
The Supercritical Carbon Dioxide Corrosion Test Facility is equipped with 3 high-temperature, high-pressure vessels and a gas-phase Fourier transform infrared spectrometer (FTIR) for simultaneous in situ monitoring of key contaminants. This paper outlines the capabilities of this new National Institute of Standards and Technology facility.