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Nickel-Cobalt Electroplating as a Protection Against Environmentally Assisted Cracking of Coated High-Strength Steel Bolts in Seawater

Hydrogen embrittlement has long been one of the most troublesome phenomena related to materials’ failures in the widespread Oil and Gas industry and yet it is the cause of recent failures and subject of new studies and analyses. Hydrogen embrittlement a form of environmentally assisted cracking (EAC) occurs when a material’s mechanical strength is weakened by the penetration of atomic hydrogen inside the material; the hydrogen sources are diverse and they all intervene in this phenomenon. In plated bolts the coating’s application may induce the penetration of hydrogen into the base-material cathodic protection by sacrificial coatings or impressed current may also have similar effect. The purpose of the present work is addressing the influence of different metallic coatings on the amount of hydrogen present in the steel bolting substrate in service conditions and relate it to the extent of hydrogen embrittlement; by co-relating environment stress and materials properties this investigation attempts to present safe alternatives to prevent hydrogen embrittlement failures.The tested samples were B7M ASTM A193/A193M bolts and 2HM ASTM A194/A194M nuts with the following coating conditions: 1) No coating 2) Zn plating 3) Zinc-Nickel plating and 4) Ni-Co ASTM B994 SC 18 Class 1 electroplating. Potentiodynamic tests in simulated sea-water solution evaluated the kinetics for hydrogen production on the different materials. Determination of hydrogen permeation into the substrate across the coatings was carried out in a Devanathan–Stachurski cell. Cathodic protection of -1.1 V vs Ag/AgCl in simulated seawater solution was applied to tensile samples varying the environmental pressure and the exposure time before breakdown in air. The results showed an outstanding performance of the Nickel-Cobalt coating compared to the sacrificial coatings; sacrificial coatings produced large currents by the cathodic reaction and allowed hydrogen penetration to the base-material Nickel-Cobalt produced less current and the permeation was much lower. The mechanical tests showed that Nickel-Cobalt is not affected by the cathodic charging while the tested sacrificial coatings reduce their mechanical resistance in a 50%.The results from this effort have an outstanding relevance in offshore and subsea deep-water drilling and production equipment that depends on high strength carbon and low allow steels. Nickel-Cobalt alloy ASTM B994 is proposed as the emerging technology for carbon and high strength steel bolts to be used in marine environment and subsea where failure is not an option.

Product Number: 51319-13270-SG
Author: Omar Rosas-Camacho
Publication Date: 2019
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Picture for Effect of Cyclic Torquing on the Corrosion Resistance and Nut Factor Consistency of Coated High- Strength Steel Bolting
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Effect of Cyclic Torquing on the Corrosion Resistance and Nut Factor Consistency of Coated High- Strength Steel Bolting

Product Number: 51319-13268-SG
Author: Omar Rosas-Camacho
Publication Date: 2019
$20.00

Almost every piece of equipment and machinery in the Oil and Gas industry requires the use of bolted joints due to numerous advantages that they offer regarding productivity and maintenance however these advantages vanish by inadequate materials selection and installation procedures. Most anti-corrosion coatings applied to bolts do not offer a consistent tightening and they are affected by torqueing during assembly; the nut factor relates the bolt’s installation torque to the tension required to tighten the bolt maintaining a consistent nut factor would solve problems such as over-torquing and corrosion resulting from the coatings peeling-off which may lead to leaking from the joint and even to joint failure. Organic coatings have historically suffered from flaking and peeling when torqued hence metallic coatings such as Ni-Co electroplating may offer a more reliable performance.In order to obtain experimental data comparing the behavior of coatings used in bolted joints simulating service conditions cyclic torquing (up to 5 cycles) was applied to fasteners with different coatings and the nut factor and corrosion resistance was evaluated. The tested samples were B7M ASTM A193/A193M bolts and 2HM ASTM A194/A194M nuts with the following coating conditions: 1) No coating 2) Ni-Co Electroplating 3) zinc undercoat with PTFE topcoat and 4) TSA / PTFE. All samples were tested with dry runs (no lubricant) and two different commercial lubricants. A Skidmore-Wilhelm load cell was used to apply the cyclic torquing and to calculate the nut factor on each cycle. Corrosion tests were performed before and after torquing following ASTM G59 standard and environmental exposure following ASTM B368 standard to evaluate the materials corrosion resistance without torque. Ni-Co electroplating showed a better performance compared to the other tested coatings it offered the highest nut factor consistency and the lowest corrosion rate after the cyclic torqueing and after environmental exposure.The main impact of this work is providing consistent and reliable test data about nut factor and corrosion resistance of coatings; this data can be used to compare available coated fasteners for selection of the best solution for bolting in oilfield and industrial application. Ni-Co electroplating is featured as a coating that provides corrosion resistance and nut factor consistency regardless the number of assembly/disassembly cycles it is proposed as a solution to avoid joint leaking and likely catastrophic failures.

Picture for 08025 Adhesion and Corrosion Perfromance of Nanostructured Nickel and Cobalt-Based Coatings
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08025 Adhesion and Corrosion Perfromance of Nanostructured Nickel and Cobalt-Based Coatings

Product Number: 51300-08025-SG
ISBN: 08025 2008 CP
Author: Abdelmounam M. Sherik, AbdulJalil H. Rasheed, Hassan A. Ajwad, Ali Jabran, and Roman G. Ortiguerra
Publication Date: 2008
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