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Stress corrosion cracking (SCC) initiation and growth rate testing was performed using Alloy A-286, a high-strength iron-base alloy, to evaluate for possible differences in response in boric acid solutions containing KOH vs. LiOH. PWRs are considering a switch from LiOH to KOH because of the uncertain future availability and high cost of Li. To achieve the same pH at temperature (pHT) in typical PWR primary water, the same molar concentration of Li and K is needed. The atomic weight of K is 39.1, which is 5.63 higher than the atomic weight of Li at 6.94, so 1 ppm Li yields the same pHT as 5.63 ppm K. The conductivity differs somewhat because of difference in the mobility of Li+ and K+.
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Stress corrosion cracking (SCC) has been observed for over six decades in light water reactors structural components, with wide variations in the rate of SCC initiation and crack growth. Newer materials have been adopted in the last three decades, primarily the ~30% Cr Alloy 690 (UNS N06690) and its weld metals, Alloy 52 (UNS W86052) and Alloy 152 (UNS W86152). These materials were initially viewed as immune to SCC, but are now recognized to be susceptibility to SCC, and can exhibit high growth rates in some conditions.
There is extensive evidence from laboratory data and plant experience of the SCC susceptibility of Alloy 82 weld metal in both BWR and PWR environments. Two international expert panels evaluated laboratory data under PWR conditions and created disposition curves to address the effects of stress intensity factor (K), temperature, and other factors. Another expert panel is creating a dispositioncurve under BWR conditions for K, temperature, corrosion potential, impurities, and other factors. Nickel alloy weld metals at lower Cr levels (~15% Cr for Alloy 182 and ~20% Cr for Alloy 82) are more susceptible to SCC than weld metals of higher Cr content (~30% Cr for Alloy 52/152). This paper focuses on on-thefly effects on SCC growth rate of Alloy 82 weld metal in BWR environments of corrosion potential, waterpurity and temperature.
Unbonded flexible pipes used for transporting process fluids in offshore oil and gas production systems have a complex structure, with alternate polymer and metallic layers. Tensile armors are metallic layers constructed by the helical wrapping of high strength carbon steel wires, and they are responsible for the integrity of the pipe. These armors provide axial strength and torsion resistance to the pipe so that it can sustain its own weight and resist to stresses associated to environmental conditions and vessel motion.
On July 8th, 1986, an 8-inch pipeline transporting gasoline ruptured in Mounds View, Minnesota. Vaporized gasoline combined with air and liquid gasoline flowed along neighborhood streets. Approximately 30 minutes later, a vehicle entered the area igniting the gasoline vapor.
Like many other areas Phoenix Arizona has unique coatings/linings guide specifications for secondary containment structures. Each entity drafts specifications to fit the particular needs of the project. Each specification has nuances that make it unique. The one thing the majority of them have in common is ACCOUNTABILTY . The word alone should keep everyone on their toes. The focus of this paper is to look at a few nuances the City of Phoenix brings to the table which may or may not make you think.
This work provides an overview of solution vinyl coating history and formulation as well as results and discussion for preliminary testing. Corrosion performance and material properties using modern laboratory techniques are needed to provide a benchmark for the development or evaluation of next generation polymer coatings that may someday provide a green alternative to the legacy vinyl systems.
Thin film electrolyte electrochemical tests have been conducted using a segmented, multi electrode sensor with an artificial crevice to quantify the interaction of crack tip and crack mouth during cyclic atmospheric corrosion tests.
Explains why concrete floors need protective treatments, identifies two main categories of protective treatments, and recommends appropriate protective treatments based on purposes and finishes of concrete floors.