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Picture for Fatigue Loading of Test Specimens with Galvanically Induced Corrosion Damage Provides New Insight to Guide Fracture Mechanics Modeling
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Fatigue Loading of Test Specimens with Galvanically Induced Corrosion Damage Provides New Insight to Guide Fracture Mechanics Modeling

Product Number: 51324-20989-SG
Author: Thomas Curtin; Sharon Mellings; Ivan Karayan; Robert Adey; Joe Indeck
Publication Date: 2024
$40.00
Airframe structural components commonly experience galvanic damage at dissimilar metal connections following deterioration of insulating sealants or breakdown in coating protection systems. Of particular concern is the often-hidden corrosion damage that occurs inside fastener holes. Aggressive electrolytes can develop in these occluded spaces leading to the formation of multiple crack initiation sites and a compromise in the structural integrity of the component. To investigate this type of damage, laboratory testing was undertaken to evaluate fatigue life in AA 7075-T651 dog-bone specimens that included side holes fitted with CFRP inserts. The CFRP insert was used to introduce galvanic damage under thin film atmospheric corrosion conditions but removed prior to actual fatigue testing. Fatigue tests were conducted under constant amplitude loading, at R-ratios of 0.05, 0.6, and 0.89, in both air and 4.5M NaCl solution. Using a three-dimensional, fatigue crack growth (FCG) program, BEASY, complex crack propagation path evolution, and transition from surface flaw to through-crack was accurately represented. By selecting appropriate crack growth kinetics, the environmental effects on fatigue life were quantitatively determined for different modeling scenarios. Fractographic images of crack initiating features (corrosion pits, constituent particle clusters) were used to guide the location and sizing of initial flaws. Fatigue crack growth kinetic data, collected in both air and NaCl solution, was used to drive crack growth simulations. Modeling scenarios included the propagation of both single dominant flaws and multiple interacting flaws; the FCG life was evaluated for each case. This modeling work provides new insight for understanding how advanced fracture mechanics modeling capability can be used to improve life prediction of corroded components.
Picture for Feasibility Journey - Feasibility of Repurposing Existing Natural Gas Network to Transport Hydrogen - Natural Gas Blends at the Distribution Leve
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Feasibility Journey - Feasibility of Repurposing Existing Natural Gas Network to Transport Hydrogen - Natural Gas Blends at the Distribution Level

Product Number: 51324-20936-SG
Author: Saba N. Esmaeely; Shane Finneran; Andrew Cummings; Daan Jonas Hottentot Cederløf ; Sander Gersen
Publication Date: 2024
$40.00
Decarbonization of energy systems requires transitioning existing energy systems to use with low carbon sources. As part of such transitions, existing natural gas networks are being evaluated for compatibility with transporting hydrogen – natural gas (H2 – NG) blends, as a steppingstone to potentially transport 100% hydrogen. Utilizing the existing networks provides opportunities for time and cost-efficient transitions overcoming the high cost of, and public resistance to, building new infrastructures. A comprehensive, system-wide assessment of existing infrastructure is the first step in determining the feasibility of such transitions, from both technical and safety aspects. Such an assessment should consider the potential challenges that are generally recognized with hydrogen or hydrogen - natural gas blends and evaluate potential impacts on the materials, operational, and safety and system performance characteristics of the systems. A thorough assessment should encompass a study of the entire network including the feasibility from multiple facets in order to provide an acceptable range of H2 concentration (H2%) to be safely blended with natural gas without substantial modification to the existing infrastructure. This should include the compatibility of the material and equipment throughout the entire network with H2, considering material interaction, system integrity, process and performance, equipment accuracy and functionality, chemical compatibility, storage and handling, and customer (i.e., end-use) compatibility. The current paper portrays the steps and challenges that should be considered in the feasibility assessment of each material population, end use and equipment population at the distribution level.
	Picture for Field Applicable PVDF Corrosion Protection Coating for Marine Assets
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	Picture for Field Applicable PVDF Protection Coating for Corrosion and Carbonation Protection of Reinforced Concrete Structure
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Field Applicable PVDF Protection Coating for Corrosion and Carbonation Protection of Reinforced Concrete Structure

Product Number: 51324-20849-SG
Author: Kevin Chung; Robert Gill; Thomas E. Pizanowski; Fred Lo; Maurice Leblon
Publication Date: 2024
$40.00
The sudden and unforeseen 2021 collapse of the 12-story beachfront condominium in the Miami suburb of Surfside, Florida, United States is a wakeup call for building safety particularly to those older buildings facing the same seaside environment. In this paper, the authors provide test data and proven evidences in related fields for a surface, field applicable PVDF coating solution that arguably can arrest and stop further concrete degradation and rebar corrosion of reinforced concrete structures and buildings. A field applicable (by brushing, roller coating, or spraying) patent-pending PVDF coating when applied on the outside of the reinforced concrete structure, can provide protection for preventing concrete from carbonation and other chemical reactions and protect the steel rebar from corrosion. For a thickness of 30 µm 100% PVDF coating, established various scientific data and experiments reported here can provide more than 100 times that of the epoxy coated rebar in terms of corrosion protection by blocking off moisture and corrosive gases from penetrating through the thin field applicable PVDF concrete coating. In the experiments of exposing reinforced concrete subjected to saline water exposure, the rebars encased in concrete coated with the field applicable PVDF coating in comparison to those without PVDF coating showed the additive characteristics of concrete and that of the PVDF coating along with the synergistic aspect of PVDF coating on top of concrete also protected the concrete from the chemical reactions with the corrosive water laden with dissolved salt ions.
Picture for Field Case Study: Impact of Corrosion Inhibitor on Scale Control
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Field Case Study: Impact of Corrosion Inhibitor on Scale Control

Product Number: 51324-20631-SG
Author: Alex Yi-Tsung Lu; Zhiwei Yue
Publication Date: 2024
$40.00
Mineral scale deposition and pipeline corrosion are two of the most common challenges that require chemical treatment in oil wells. Combination products including scale inhibitor (SI), corrosion inhibitor (CI) packages, surfactants, and other chemical additives are well accepted as an integrated solution to flow assurance and asset integrity problems. In this work, a case study in the Permian Basin field demonstrates a certain type of combination product exhibiting lower performance than expected. The raw material interference on the scale inhibitors was investigated and presented with detailed laboratory data. A series of laboratory tests were conducted to investigate the impacts on performance from the chemicals in the combination product. In the dynamic tube blocking test, the phosphonate-based SI shows much weaker performance in the presence of certain active CI components, while other raw materials (surfactants and quaternary amine) had a minor effect. Further bottle tests revealed a calcite inhibition drop from complete inhibition to 30% and 40% inhibition in the two phosphonate-based SI chemistries in the presence of the active component, respectively. In the additional barite inhibition tests, no significant impact on the SI performance was observed. Contrary to the previous literature reports about common CI chemicals, this active component expressed significantly adverse impacts on the SI performance for calcite prevention. This study demonstrates a root cause analysis for the adverse effect of certain active CI components on the scale prevention and suggests the impact of the CI package on SI should be carefully investigated in the product selection. A thorough evaluation of combination product performance is recommended before the field application.