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99460 A BARE METAL REFERENCE ELECTRODE FOR APPLICATION UNDER HIGH-TEMPERATURE, HIGH-PRESSURE AND HIGH-RADIATION CONDITIONS

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Product Number: 51300-99460-SG
ISBN: 99460 1999 CP
Author: L. Yang
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A bare metal electrode device that was used to provide a pseudo reference potential was tested under high temperature and high-pressure conditions. This reference potential was obtained from the polarization curve of the evolution reaction of hydrogen or oxygen. A cyclic voltammetric method was used in the experiments to obtain the polarization curve for the evolution reactions. Experimental results show that the measured potential of a stainless steel electrode and a stainless steel vessel with respect to the new reference potential were consistent with the values measured against an Ag/AgCl reference electrode. As only bare metal electrodes are required in the reference electrode device, it is robust for applications under high-temperature, high-pressure and high-radiation conditions or in locations difficult to access.

Keywords: reference electrode, reference potential, corrosion potential, electrochemical potential, high temperature solution, high pressure solution, high temperature corrosion, nuclear reactor coolant, radiation field
A bare metal electrode device that was used to provide a pseudo reference potential was tested under high temperature and high-pressure conditions. This reference potential was obtained from the polarization curve of the evolution reaction of hydrogen or oxygen. A cyclic voltammetric method was used in the experiments to obtain the polarization curve for the evolution reactions. Experimental results show that the measured potential of a stainless steel electrode and a stainless steel vessel with respect to the new reference potential were consistent with the values measured against an Ag/AgCl reference electrode. As only bare metal electrodes are required in the reference electrode device, it is robust for applications under high-temperature, high-pressure and high-radiation conditions or in locations difficult to access.

Keywords: reference electrode, reference potential, corrosion potential, electrochemical potential, high temperature solution, high pressure solution, high temperature corrosion, nuclear reactor coolant, radiation field
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