Server maintenance is scheduled for Saturday, December 21st between 6am-10am CST.

During that time, parts of our website will be affected until maintenance is completed. Thank you for your patience.

Search
Filters
Close

99452 DEVELOPMENT OF FAST ALGORITMS FOR ESTIMATING STRESS CORROSION CRACK GROWH RATE IN SENTIZED STAINLESS STEELS IN BOILING WATER REACTOR COOLANT ENVIRONMENTS

Product Number: 51300-99452-SG
ISBN: 99452 1999 CP
Author: M, Urquidi-Macdonald, G. R. Engelhardt and D. D. Macdonald
$0.00
$20.00
$20.00
A simplified method is proposed for modeling the chemistry and potential distribution in a stress corrosion crack in sensitized stainless steel in boiling water reactor (BWR) coolant environments. The model is based on an assumption that only those species that are present at the largest concentrations in the crevice determine the potential distribution down the crack. The advantage of this method is that it permits simplification of the mathematics and allows predictions to be made of the potential and concentration distributions without knowing various parameters, such as the equilibrium constants for homogeneous chemical reactions in the cavity and diffision coefficients of species that are present at relatively low concentrations near the crack tip. In some important cases, analytical expressions can be obtained for the pH, potential near the crack tip, and crack propagation rate. The conditions for which the potential on the crack flanks and in the vicinity of the crack tip coincides with the free corrosion potential in the local environment, and hence for which there exists a balance between rates of the local anodic and cathodic partial processes, are determined. The impact of the potential drop in the external environment on the potential and concentration distributions down the crack and on the crack propagation rate is also investigated. Excellent agreement is obtained between calculated and measured crack growth rates. Keywords: stress corrosion cracking, crack growth rate, Boiling Water Reactors
A simplified method is proposed for modeling the chemistry and potential distribution in a stress corrosion crack in sensitized stainless steel in boiling water reactor (BWR) coolant environments. The model is based on an assumption that only those species that are present at the largest concentrations in the crevice determine the potential distribution down the crack. The advantage of this method is that it permits simplification of the mathematics and allows predictions to be made of the potential and concentration distributions without knowing various parameters, such as the equilibrium constants for homogeneous chemical reactions in the cavity and diffision coefficients of species that are present at relatively low concentrations near the crack tip. In some important cases, analytical expressions can be obtained for the pH, potential near the crack tip, and crack propagation rate. The conditions for which the potential on the crack flanks and in the vicinity of the crack tip coincides with the free corrosion potential in the local environment, and hence for which there exists a balance between rates of the local anodic and cathodic partial processes, are determined. The impact of the potential drop in the external environment on the potential and concentration distributions down the crack and on the crack propagation rate is also investigated. Excellent agreement is obtained between calculated and measured crack growth rates. Keywords: stress corrosion cracking, crack growth rate, Boiling Water Reactors
PRICE BREAKS - The more you buy, the more you save
Quantity
1+
5+
Price
$20.00
$20.00
Product tags
Also Purchased
Picture for 99451 METALLURGICAL FACTORS INFLUENCING THE
Available for download

99451 METALLURGICAL FACTORS INFLUENCING THE SUSCEPTIBILITY OF NON-SENSITIZED STAINLESS STEEL TO INTERGRANULAR STRESS-CORROSION CRACKING IN HIGH-TEMPERATURE, HIGH-PURITY WATER ENVIRONMENTS

Product Number: 51300-99451-SG
ISBN: 99451 1999 CP
Author: Masatsune Akashi, Guen Nakayama, Hajime Komatsu , Seizaburo Abe
$20.00
Picture for 99465 GALVANIC CORROSION - EFFECT OF
Available for download

99465 GALVANIC CORROSION - EFFECT OF ENVIRONMENTAL AND EXPERIMENTAL VARIABLES

Product Number: 51300-99465-SG
ISBN: 99465 1999 CP
Author: Ajit K. Roy, Dennis L. Fleming, Beverly Y. Lum
$20.00
Picture for 99450  CHARACTERIZATION OF INTERGRANULAR STRESS-
Available for download

99450 CHARACTERIZATION OF INTERGRANULAR STRESS-CORROSION CRACKING INITIATION IN TYPE 304 STAINLESS STEEL USING SCANNING PROBE MICROSCOPY

Product Number: 51300-99450-SG
ISBN: 99450 1999 CP
Author: A.W. Phelps, G.H. Koch, A.K. Agrawal, and M.P.H. Brongers
$20.00