The prediction of carbon steel corrosion in sour acid gas environment is
more challenging than that in sweet acid gas environments, because in the
former environments various iron sulfide scales can form that result in different
corrosion mechanisms. A unique approach was developed to study the complex
sour acid gas corrosion behavior, which combined the use of long-term corrosion
testing data, facility life prediction data obtained from extreme value statistics
method (EVS), and validation with long-term field caliper data. This approach
was used to evaluate the applicability of carbon steel for downhole tubing in sour
acid gas environments, in order to achieve optimum capital expenditure and
long-term facilities integrity.
The effects of three key parameters on L80 carbon steel tubing corrosion were
investigated. These parameters were H2S concentration, chloride level, and test
duration. Laboratory data combining EVS method were used to predict the tubing
life, which were then compared with field caliper inspection data. This
comparison showed that predictions based on long-duration laboratory data were
consistent with the available field caliper data. It also indicated that field caliper
inspection data provided reliable information for tubing life predictions, which
complemented mechanistic understanding from laboratory studies.
Keywords: iron sulfide, scale, carbon steel, H2S corrosion, chloride