The extent of the oxygen reduction reaction in concrete was evaluated for ~9% Cr rebar
approaching the ASTM A1035 specification and compared to that of conventional carbon steel
rebar, at ages of up to ~ 1year. Cathodic strength was measured by the cathodic current
density developed at -0.35 and -0.40 V (Cu/CuSO4) in cyclic cathodic potentiodynamic
polarization tests, both in the as-received condition with mill scale, and with scale removed by
glass bead surface blasting. In both conditions the ~9% Cr alloy was a substantially weaker
cathode, by a factor of several fold, than carbon steel. Within each material, the surface
blasted condition yielded also much lower cathodic current density than the as-received
condition. These trends indicate an additional benefit in the application of ~9% Cr alloy as an
alternative material to CS. There was strong correlation between the charge storage capability
of the interface and the extent of cathodic reaction of oxygen. The result cannot be ascribed
solely to differences in effective surface area between the different materials and conditions.
Key Words: 9% Cr, steel reinforcement, rebar, concrete, cathodic reaction, mill scale, glass
bead blasting, corrosion