The reduction of boron in permeate water is currently practiced by using a
secondary pass reverse osmosis (RO) system whereby the pH of the feed is
increased above pH 10 with a recovery of greater than 90%. These conditions
lead to fouling of predominantly of magnesium hydroxide onto the membrane
thus reducing its efficiency.
An investigation was carried out to study the fouling under conditions of high pH
and recovery on a membrane. A new method was developed to study the
deposition of magnesium hydroxide under dynamic conditions. The findings from
this work show that there are significant differences in precipitation in the bulk
solution phase and at the membrane surface. This method was used to
demonstrate the efficacy of an antiscalant to control magnesium hydroxide
precipitation under high pH and high recovery conditions.