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07581 Environmental and Geometrical Conditions to Sustain Crevice in Alloy 22

Picture for 07581 Environmental and Geometrical Conditions to Sustain Crevice in Alloy 22
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Product Number: 51300-07581-SG
ISBN: 07581 2007 CP
Author: Ricardo M. Carranza, Martin A. Rodriguez, and Raul B. Rebak
Publication Date: 2007
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Alloy 22 (N06022) is highly resistant to localized corrosion. Under aggressive environmental conditions Alloy 22 may be susceptible to crevice corrosion in hot chloride (Cl-) solutions. The objective of the present work was to explore the environmental and geometrical conditions for crevice corrosion to occur. Electrochemical tests were performed using PCA and prismatic mill annealed Alloy 22 specimens in chloride solutions. Crevice corrosion current density was found to be a function of applied potential. iCREV values ranged from 40 µA/cm2 to 20 mA/cm2. Such low values of current density explained the absence of pitting corrosion in Alloy 22 at any potential. Decreasing of the effective diffusion distance in a propagating crevice is thought to cause crevice corrosion stifling or repassivation after long anodic polarization. Crevice corrosion breakdown potential is expected to decrease with potential scan rate, approaching repassivation potential for low scan rates. The lowest corrosion potential of Alloy 22 in hydrochloric acid solutions at which active corrosion exists was proposed as the lowest possible repassivation potential for crevice corrosion.
Alloy 22 (N06022) is highly resistant to localized corrosion. Under aggressive environmental conditions Alloy 22 may be susceptible to crevice corrosion in hot chloride (Cl-) solutions. The objective of the present work was to explore the environmental and geometrical conditions for crevice corrosion to occur. Electrochemical tests were performed using PCA and prismatic mill annealed Alloy 22 specimens in chloride solutions. Crevice corrosion current density was found to be a function of applied potential. iCREV values ranged from 40 µA/cm2 to 20 mA/cm2. Such low values of current density explained the absence of pitting corrosion in Alloy 22 at any potential. Decreasing of the effective diffusion distance in a propagating crevice is thought to cause crevice corrosion stifling or repassivation after long anodic polarization. Crevice corrosion breakdown potential is expected to decrease with potential scan rate, approaching repassivation potential for low scan rates. The lowest corrosion potential of Alloy 22 in hydrochloric acid solutions at which active corrosion exists was proposed as the lowest possible repassivation potential for crevice corrosion.
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