A model is presented for the prediction of the corrosion rate by CO2 under dewing conditions. A mechanistic approach is developed that takes into consideration the hydrodynamics, thermodynamics, heat and mass transfer, chemistry, and electrochemistry during the phenomenon of Top-Of-The Line corrosion. This model is validated by experimental data. It offers a better insight on the role played by primary parameters such as the temperature, the total pressure, the partial pressure of CO2, the gas velocity, and the condensation rate.
Key words: modeling of CO2 corrosion, Top-of-the Line Corrosion, non-condensable gas, condensation rate, corrosion rate, scaling tendency, protective scale, superficial porosity.