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01388 Effect of ID Surface Modification on Carburization of Ethylene Furnace Tubes

Picture for 01388 Effect of ID Surface Modification
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Product Number: 51300-01388-SG
ISBN: 01388 2001 CP
Author: Arun R. Kurlekar, George T. Bayer, Gerald E. Gapinski
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Results are presented of a metallurgical evaluation of diffusion coated, micro-alloyed HP-Nb (HP-Nb MA) ethylene furnace tubes after 27 months in service in a furnace. The diffusion coating system applied to the ID surfaces of the tubes by a modified pack cementation process was a bi-diffused aluminum-chromium-silicon system. Results indicate that the coating was thermally stable and successful at eliminating carburization at temperatures exceeding the maximum design temperature for the furnace. Tube sections excised from a coil section exhibiting flame impingement damage confirmed the coating prevented carbon ingress at tube metal temperatures of at least 2050 ° F (1121 ° C). Earlier published work verified the ability of the coating system in reducing coke formation during the first 14 months of service. Details of additional research to determine detailed phase characterization and the mechanisms of protective action are discussed.
Results are presented of a metallurgical evaluation of diffusion coated, micro-alloyed HP-Nb (HP-Nb MA) ethylene furnace tubes after 27 months in service in a furnace. The diffusion coating system applied to the ID surfaces of the tubes by a modified pack cementation process was a bi-diffused aluminum-chromium-silicon system. Results indicate that the coating was thermally stable and successful at eliminating carburization at temperatures exceeding the maximum design temperature for the furnace. Tube sections excised from a coil section exhibiting flame impingement damage confirmed the coating prevented carbon ingress at tube metal temperatures of at least 2050 ° F (1121 ° C). Earlier published work verified the ability of the coating system in reducing coke formation during the first 14 months of service. Details of additional research to determine detailed phase characterization and the mechanisms of protective action are discussed.
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01389 LOCAL HEAVY CARBURIZATION OF OLEFIN PYROLYSIS FURNACE TUBE

Product Number: 51300-01389-SG
ISBN: 01389 2001 CP
Author: A. Kh. Bairamov and R. Bradley
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02386 A NEW CARBURIZATION RESISTANT ALLOY FOR ETHYLENE PYROLYSIS FURNACE TUBES

Product Number: 51300-02386-SG
ISBN: 02386 2002 CP
Author: Y.Nishiyama, H.Semba, K.Ogawa, Y.Yamadera, Y.Sawaragi, and S.Kinomura
Publication Date: 2002
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A new wrought alloy has been developed for use as furnace tubes in ethylene pyrolysis plants. This alloy has an excellent carburization resistance due to uniform formation of protective Al2O3 oxide scale on the metal surface. Laboratory corrosion tests have been carried out to evaluate carburization resistance of the developed alloy.
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01392 A LOW COKING AND CARBURIZATION RESISTANT COATING FOR ETHYLENE PYROLYSIS FURNACES

Product Number: 51300-01392-SG
ISBN: 01392 2001 CP
Author: Ted Redmond, Dr. Yan Chen, Arthur Bailey, John Page
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