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00031 CO2 CORROSION UNDER SCALING CONDITIONS - THE SPECIAL CASE OF TOP-OF-LINE CORROSION IN WET GAS PIPELINES

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Product Number: 51300-00031-SG
ISBN: 00031 2000 C
Author: B.F.M. Pots and E.L.J.A. Hendriksen
Industry: Pipelines, Tanks, and Underground Systems
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This paper addresses pipeline conditions leading to a protective corrosion product scale. The special case of Top-Of-Line (TOL) corrosion will be considered in detail. Methods for TOL corrosion rate prediction are discussed and compared with new and old experimental data. Data best agree with the so-called iron super-saturation model. Avoiding high water condensation rates resulting from a low pipe wall temperature can obviate TOL corrosion. The protective corrosion product scale formed in TOL corrosion may be jeopardized by the presence of organic acids. Keywords: pipeline, carbon dioxide, corrosion, condensation, scaling, iron carbonate, organic acids
This paper addresses pipeline conditions leading to a protective corrosion product scale. The special case of Top-Of-Line (TOL) corrosion will be considered in detail. Methods for TOL corrosion rate prediction are discussed and compared with new and old experimental data. Data best agree with the so-called iron super-saturation model. Avoiding high water condensation rates resulting from a low pipe wall temperature can obviate TOL corrosion. The protective corrosion product scale formed in TOL corrosion may be jeopardized by the presence of organic acids. Keywords: pipeline, carbon dioxide, corrosion, condensation, scaling, iron carbonate, organic acids
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